The greenhouse effect is an important part of the Earth's climate without which the planet would be a far colder place. The effect is natural and not new. When sunlight hits the surface of the earth it is absorbed and the visible light (short wave radiation) is converted to heat (infrared or long wave radiation) (Fig. 1) which is radiated back into the atmosphere towards space.
Figure 1. A schematic of the electromagnetic spectrum, showing the Sun's energy output in relation to wavelength.
Some gases in the atmosphere (the so called greenhouse gases: such as carbon dioxide, water vapour, methane, etc.) absorb the infra red radiation (heat) which is converted into kinetic and potential energy. Eventually these molecules then emit heat back into the atmosphere as infrared radiation. Some of this infrared radiation is absorbed by other greenhouse gases and some is absorbed at the earth's surface and the cycles of absorption, conversion and emission are repeated (Fig. 2). Essentially this process slows the loss of heat to space, keeping the earth's surface warmer than it would be without the greenhouse gases. Without this “greenhouse” the Earth's atmosphere would be an average of about 30-35 oC cooler and life as we know it would not exist.
Figure 2. An overview of the Greenhouse Effect. From IPPC Working Group 1 contribution, Science of Climate Change, Second Assessment Report 1996 .
The enhanced greenhouse effect, sometimes referred to as climate change or global warming, is the impact on the climate from the additional heat retained due to the increased amounts of carbon dioxide and other greenhouse gases that humans have released into the earths atmosphere since the industrial revolution.
Since the mid 1800's the average concentration of CO2 in the earth's atmosphere has risen from about 280 parts per million (ppm) to just over 383 ppm in 2007, and methane from about 800 part per billion (ppb) to around 1790 ppb in 2008 (Fig. 3).
Figure 3. Global atmospheric concentrations of four greenhouse gases. From the IPCC 2007 4th Assessment Report .
While these changes represent only a very small change to the overall composition of the earth's atmosphere, it is a significant change to its capacity to absorb and emit heat. The main contributors are changes to the carbon cycle that have led to increased levels of carbon dioxide in the earth's atmosphere in the last 200 years. These include reduced CO2 removal and storage through deforestation; direct CO2 production from the burning of fossil fuels and CO2 released from cement production.
The increased release of nitrogen oxides (NOx) from burning fossil fuels and soil denitrification (particularly with the introduction of high nitrogen fertilizers) and intensive production of livestock such as cows and pigs which produce methane have also contributed to the enhanced greenhouse effect.
The differing chemical structures of these gases produce a different absorption spectra or wavelengths of radiation which they will absorb or let through. An important aspect of this is that even if the atmosphere is saturated with water vapour there are wavelengths of infrared radiation that it will not be absorbed. However, CO2 and other greenhouse gases can absorb the infrared radiation at the wavelengths missed by water vapour.
Figure 4. The radiation Absorption characteristics of Water Vapour and Carbon Dioxide. From the Bureau of Meteorology (BOM) .
The capacity for a gas to absorb long wavelength (Infrared) radiation and the length of time it spends in the atmosphere both impact on its potential to act as a greenhouse gas. This potential is often expressed as its CO2 equivalent, or the number of equivalent molecules of CO2 it would take to absorb as much heat as one molecule of the gas in question over a given time period (usually 100 years). The CO2 equivalents of some greenhouse gases are shown in table 1 below.
|HFC's||140 ~ 11,700|
|PFC's||6,500 ~ 9,200|
Table 1. CO2 equivalents of some greenhouse gases. From the US Environmental Protection Agency .
Note that while methane (CH4) and N2O both absorb more heat per molecule than CO2, CO2 concentrations are much higher (100 -100 times higher respectively) and therefore have more overall affect on the enhanced greenhouse affect. Residence time plays an important role as well as concentration. While water vapour is by far the greatest contributor to the natural greenhouse effect, it spends so little time in the atmosphere (days rather than centuries) that it is not well mixed and thus its affects on temperature are short lived and very localised.
While we can directly measure the levels of CO2 and other greenhouse gases in the atmosphere and we know how they have changed in the past, the extent to which their concentrations will change in the future is uncertain (Fig. 5). How much greenhouse gas will be emitted in the future is dependent on a number of complex factors, such population change, economic development, changes to technology along with social and political ideology. Projections of future emissions of greenhouse gases are made based on scenarios, or plausible descriptions of the future. A scenario provides a set of assumptions that describe what might happen in the future . As the interactions between each of the factors within a scenario and how each of the factors will affect greenhouse emission are not completely understood, uncertainty is introduced at every step of the projection process. The possible error in projected emissions is carried into the projected levels of greenhouse gases and further compounded when a projection of temperature change is made from the greenhouse gas concentrations.
Figure 5. Flow chart illustrating that uncertainty is introduced into predictions of impacts at every step, and these uncertainties accumulate. From Pittock 2005 
The uncertainty of the temperature projections are further increased due to our limited understanding of the exact sensitivity of climate to various concentrations of greenhouse gases, i.e. how much will temperature rise from a given increase in CO2 levels (Fig. 6). This is even further complicated by the issue of feedbacks in which higher temperatures will lead to increased release of greenhouse gases leading to even higher temperatures and thus releasing more greenhouse gas and so on. An example would be the release of methane from permafrost (ground currently frozen all year round) as it thaws in the Northern Hemisphere.
Figure 6. Projections of a) CO2 emissions, b) atmospheric CO2 concentrations, and d) temperature change, associated with the IPCC emission scenarios. Note the levels of uncertainty associated with the projections of temperature change. From the IPCC special report on emission scenarios 2000 .
There are various flow on effects of global temperature increase due climate change. These include changes to rainfall conditions, storm intensity or frequency and sea level rise. Recent work has begun understanding the impact climate change has on these environmental parameters. For example Timbal et al  has attributed the drying trend in south-west Australia using natural and human induced forcing factors. This studied recognised the anthropogenic contribution to the drying trend. The South Eastern Australian Climate Initiative have likewise studied climate drivers and future projections for the Murray Darling Basin. The impact of clouds and aerosols on climate trends is also important for future climate predictions and the CSIRO have recently completed work studying the influence of aerosols on rainfall patterns.
Air temperature is regularly measured across Australia. The map in figure 7 shows the average trend in annual mean temperature for areas in Australia for the period 1950-2008 as degrees Celsius per decade, eg. 0.2 oC/10yrs for 50 years equals a 1 oC increase in mean annual temperature since 1950.
Figure 7. Average trend in annual mean temperature in Australia (ºc/10yrs - 1950-2001) From The Bureau of Meteorology .
Rainfall is regularly measured across Australia. The map in figure 8 shows the average trend in total rainfall for Australia for the period 1950-2008 as millimetres per decade, eg. +20mm/10yrs for 50 years equals a 100 millimetre increase in average rainfall since 1950.
Figure 8. Average trend in total rainfall in Australia (mm/10yrs) 1950-2008. From The Bureau of Meteorology .
A major factor governing the form and function of coastal waterways is the availability of water. Rainfall is predicted to decrease for most of the populated areas of Australia and this will impact how much water can be collected and environmental flows. As discussed above the relationship between rainfall and runoff is not linear. Measurements taken for the reservoirs that supply Perth (Fig. 9) show that for the period between 1974 and 1996 the average rainfall decreased by 14% but the inflow to the reservoirs for the same period decreased by 48%. In the past ten years (1996-2006) the rainfall has decreased by another 7% and the inflow by another 16%. Factors such as increased evaporation and decreased soil moisture are combining with the decreased rainfall to produce a much greater decrease in inflow.
Figure 9. Total annual inflow of water (GL) received into dams near Perth, Western Australia from 1911 to 2007. Courtesy of the Water Corporation of Western Australia .
The other interesting point about this example is the apparent stepwise nature of the changes. These changes are not slow gradual variations that can be monitored and accounted for through planning or evolution. These are sudden rapid transformations in conditions that could devastate an ecosystem dependant on the inflow.
Sea level changes in response to fluctuations in ocean mass and the expansion or contraction of water as it cools or warms . Under increased global temperatures seawater expands as it warms and increases in mass due to the melting of glaciers, ice caps and ice sheets. Figure 10 shows the IPCC 2001 projected sea level compared to those observed by tide gauges and satellite altimeters for the period 1990 to 2006. The figure shows sea level rising at a rate that exceeds these initial projections. It is important to note that sea level rises at both temporal and spatial scales and thus the rise is not experienced uniformly across the globe. Sea level rise leads to a variety of problems including inundation of coastal ecosystems and infrastructure and saline intrusion into freshwater aquifers.
Figure 10. Global mean sea level from 1990 to 2006 and those projected by the IPCC 2001. Observed sea level from tide gauges (blue) and satellites (red) have tracked near the upper bound (black line) of the projections. From the CSIRO .
In Australia there have been many trends observed in a variety of ecosystems that could be the result of changes to climate. Hughes  provides a review of these changes that include:
CO2 absorption by oceans has led to a decrease in the pH of about 0.1 units from pre industrial levels. This change represents about a 30% increase in the concentration of H+ in seawater.
Studies have correlated the frequency of intense cyclones (category 4 or 5 on the Saffir-Simpson scale) with increased water temperature .
The CSIRO  has produced a series of projections for climate change in Australia using the IPCC Special Report on Emissions Scenarios . Annual and seasonal projections have been prepared for the IPCC scenarios that each describe a viable future world emission scenario. For further information on these projections see the Climate Change in Australia, technical report 2007. The projected changes in temperature and rainfall for Australia for the year 2030 are shown in figures 11 and 12 below.
Figure 11. Best estimate (50th percentile) of the changes in average temperature (°C) over Australia for 2030 using the A1B emission scenario for summer, autumn, winter, spring and annual. Reproduced with permission from CSIRO 1.
Figure 12. Best estimate (50th percentile) of predicted precipitation change for 2030 in Australia using the A1B emission scenario as a percentage of 1961 – 1990 values for summer, autumn, winter, spring and annual. Reproduced with permission from CSIRO 1.
Pittock  has produced a thorough compilation of the effects of climate change in Australia and the likely impacts of those effects. Below is a table showing projected impacts from changes to average temperature or rainfall. While some of the changes projected appear to be small, these are changes to averages which means the ranges of conditions that go into producing them will much larger. Note the severity of the consequences from seemingly small changes (1 or 2 degrees Celsius).
Listed below are some examples of the potential impacts of climate change could have on estuaries. All of these changes have the potential to alter the distribution of species.
Department of Climate Change
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